As the journey continues, there's beauty and danger in equal measure for Charley Boorman and Ewan McGrego. The duo ride their electric Harleys through the exotic and breathtaking Bolivian countryside in a tough ascent. The sixth episode showcases some of the challenges the hosts and the crew face when they scale the terrain. One of the Rivians runs into trouble while sandy roads and a heavy breeze sees Boorman take a tumble. Apart from all the accidents, the chapter also shows some quality work done by UNICEF when it comes to educating and working with the children in Bolivia.
The altitude sickness hits Taylor, their logistics man real bad and McGregor starts feeling it as well. The episode ends with a doctor heading to his hotel room to check up on him.

The Atlantic is the second largest ocean on the planet. It is the resting place of the Titanic, home to the mysterious Bermuda Triangle and is the youngest of the Earth's great oceans. It reaches depths of 8,500 metres. Oceans investigates this influential body of water from a group of islands in its western reaches - the Bahamas.

The Indians called the frozen peak of this great Alaskan mountain range Denali, or 'the high one.' Most know it as Mount McKinley. This preserved wilderness comes to life with the thaw of spring and wildlife abounds during the brief summer, only to succumb to the grip of the long winter. Watch as 5-week-old grizzly cubs play, a moose gives birth to her calf, and a wood frog survives the deep freeze of winter. Breath-taking shots of dazzling northern lights over vast and lush wilderness make this an unforgettable Eden.

As almost all animal inhabitants of Antarctica are forced to migrate north, the sea underneath the frozen ice still provides a home to many specially adapted fish whose cells are protected from freezing through an 'antifreeze' liquid. Many of them feed on the faeces of other animals. The most notable larger animal that does not migrate north is perhaps the Weddell Seal, which can be found as close as 1300 kilometres to the pole. Groups of seals tear holes into the ice to dive for food and come up to breathe. The females come back to the ice to give birth. This episode also describes primitive plant life such as lichen, which can still be found on the continent in winter, even in the extremely dry and permanently frozen valleys conditions under which dead animals can lie frozen for many centuries without decomposing. It details the life of the Emperor Penguin, 'the only birds to lay their eggs directly on ice'. While other animals retreat, Emperors migrate not just to the ice, but into the Antarctic continent. The females lay eggs which are incubated by the males under the harshest conditions on Earth (huddling closely together for warmth), while the females return to the sea.

The Russian Arctic is one of the world’s most extreme habitats, yet it is a haven for polar bears, lemmings, arctic foxes and walruses. In late August, massive muskoxen bulls gather together to compete for mating dominance. Each bull can weigh 400 kilogram’s and charge at a speed of 40 kilometres an hour; a head-to-head impact can be heard more than a kilometre away

Weather controls the distribution of freshwater on Earth. David Attenborough narrates how this uneven distribution has given rise to an incredible diversity of species and habits, from the driest desert to the lushest tropical rainforest. Featuring a colony of ants banding together into a raft every time its home in the Amazon floods, a rain frog that manages to eke out an existence in one of the world's driest habitats on Earth, and the last wild camels that survive the Gobi Desert's bitter winters by eating snow that blows in from Siberia.